4.7 Review

Etching to unveil active sites of nanocatalysts for electrocatalysis

Journal

MATERIALS CHEMISTRY FRONTIERS
Volume 5, Issue 11, Pages 3962-3985

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qm00233c

Keywords

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Funding

  1. National Research Foundation (NRF) of Korea [NRF-2020R1A2B5B03002475, 2019 R1A6A1A11044070, 2019M3E6A1064709, 2021R1A2C4001411, 2019R1A6A3A13091706, 2020R1A4A1018393]
  2. Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Korea government (MOTIE) [20203020030010]
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [20203020030010] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  4. National Research Foundation of Korea [2021R1A2C4001411, 2019M3E6A1064709, 2020R1A4A1018393, 2019R1A6A3A13091706] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Etching is an effective technique to expose catalytically active sites on the surface of nanocrystals. It can enhance catalytic activity and stability by modifying the surface structure and composition. However, there are still challenges in this field that need to be addressed for developing highly stable and active electrocatalysts.
Etching is an effective technique to expose catalytically active sites on the surface of nanocrystals by modifying the surface structure and composition. In this review, various physical and chemical etching methods, specifically developed for nanocrystal systems, as well as their advantages and disadvantages, are introduced. The surface changes in the etched nanocrystals are discussed in view of their impact on catalytic activity and stability to understand the relationship between the nanosurface and catalytic performance. Furthermore, we discuss the standing challenges and provide future research directions in this relevant field, which would lead to fruitful outcomes in developing highly stable and active electrocatalysts for sustainable energy technologies.

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