Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 32, Pages 3861-3864Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00864a
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Funding
- VILLUM Foundation for a VILLUM Young Investigator grant [15374]
- Carlsberg Foundation [CF-17-0637]
- Brdr. Hartmanns foundation
- Torkil Holm foundation
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This study reports the synthesis of pyrazine-pillared metal-organic frameworks (MOFs) through ligand substitution of Group 6 metal hexacarbonyls. The obtained frameworks have hexagonal pore channels with CO-plastered porewalls, representing the first crystallographically characterized examples of Cr(0), Mo(0), and W(0)-based MOFs. The study suggests exploring homoleptic metal carbonyls as starting materials to generate polymeric materials with low-valent metal nodes.
We report the synthesis of pyrazine-pillared metal-organic frameworks (MOFs) generated through ligand substitution of the Group 6 metal hexacarbonyls. The obtained frameworks exhibit hexagonal pore channels with CO-plastered porewalls. This series constitutes the first crystallographically characterized examples of Cr(0), Mo(0), and W(0)-based MOFs and suggests the exploration of homoleptic metal carbonyls as starting materials to generate polymeric materials with low-valent metal nodes.
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