Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 11, Issue 6, Pages 2229-2241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cy02482a
Keywords
-
Categories
Funding
- Ministry of Science and Technology, Taiwan [MOST108-2638-E-002-003-MY2, 108-2221-E-110-014-MY3, MOST 109-2636-E-007-021]
Ask authors/readers for more resources
In this study, three pyrene-based photoactive conjugated microporous polymers were synthesized and characterized, with Py-TPA-CMP exhibiting the best performance in photocatalytic H-2 production, showing high BET surface area, total pore volume, and apparent quantum yield compared to other organic porous materials.
Photoactive conjugated microporous polymers (CMPs) are emerging as porous materials capable of mediating the photocatalytic evolution of H-2 from water. In this study, we synthesized three pyrene-based CMPs (Py-F-CMP, Py-TPA-CMP, Py-TPE-CMP) through Sonogashira-Hagihara cross-couplings of 1,3,6,8-tetraethynylpyrene (Py-T, as a common monomer building block) with 2,7-dibromo-9H-fluorene (F-Br-2), tris(4-bromophenyl)amine (TPA-Br-3), and 1,1,2,2-tetrakis(4-bromophenyl)ethene (TPE-Br-4), respectively, in the presence of Pd(PPh3)(4) in DMF/Et3N. We then characterized the chemical structures, crystallinities, thermal stabilities, surface morphologies, and porosities of these three new CMPs. Brunauer-Emmett-Teller (BET) analyses and tests of photocatalytic H-2 production revealed that Py-TPA-CMP displayed the highest BET surface area (454 m(2) g(-1)), highest total pore volume (0.28 cm(3) g(-1)), highest H-2 evolution rate (19 200 mu mol h(-1) g(-1)), and highest apparent quantum yield (15.3%) when compared with those of Py-F-CMP, Py-TPE-CMP, and other organic porous materials.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available