Removal of methylene blue and lead(ii) via PVA/SA double-cross-linked network gel beads loaded with Fe3O4@KHA nanoparticles

Novel magnetic gel beads were successfully fabricated via a polyvinyl alcohol (PVA) and sodium alginate (SA) double-cross-linked network and loaded with ferroferric oxide@potassium humate (Fe3O4@KHA) nanoparticles. The PVA/SA/Fe3O4@KHA gel beads were found to exhibit an excellent removal efficiency for methylene blue (MB) dye and Pb(ii). The physicochemical properties of these gel beads were systematically characterized using Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, zeta analysis, Brunauer-Emmett-Teller analysis and vibrating sample magnetometry. The adsorption process was found to follow a pseudo-second-order kinetic model and the experimental data were in good agreement with the Langmuir model, with maximum adsorption capacity values of 781.92 and 347.19 mg g(-1) for MB and Pb(ii) at 298 K, respectively. The thermodynamic measurements demonstrate that adsorption onto these gel beads was spontaneous, endothermic, and driven by an increase in the system entropy. Furthermore, FT-IR and X-ray spectroscopy investigations demonstrate that the mechanism through which Pb(ii) was removed mainly involved chelation by the carboxyl groups, whereas MB adsorption takes place via H-bonding and electrostatic interactions. Notably, PVA/SA/Fe3O4@KHA showed high selectivity for MB adsorption. Additionally, the prepared magnetic gel beads could be readily regenerated and efficiently reused for several cycles and their excellent magnetic properties can simplify the adsorbent separation process.

Automated summary

Novel magnetic gel beads were fabricated with PVA and SA double-cross-linked network loaded with Fe3O4@KHA nanoparticles. The gel beads showed excellent removal efficiency for MB dye and Pb(ii), following pseudo-second-order kinetic model with good agreement with Langmuir model. The adsorption process was spontaneous and endothermic, with high selectivity for MB adsorption and easy regeneration for multiple cycles.