Journal
GREEN CHEMISTRY
Volume 23, Issue 6, Pages 2308-2316Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc04231e
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A polymer-bound organocatalyst for Baeyer-Villiger reaction and phenol oxidation under continuous flow conditions has been described for the first time. This catalyst showed high catalytic activities, selectivities, recyclability, and productivity, enabling the generation of a novel approach for the synthesis of benzoquinones from beta-O-4 lignin models.
A polymer-bound organocatalyst for Baeyer-Villiger reaction and phenol oxidation under continuous flow conditions is described for the first time. BAR has revealed two catalytic activities that enabled the generation of a novel approach for the synthesis of benzoquinones from beta-O-4 lignin models in a one-pot protocol. High catalytic activities (yields up to 98%), selectivities, recyclability and productivity were achieved.
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