Journal
FOOD CHEMISTRY
Volume 237, Issue -, Pages 877-886Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2017.05.116
Keywords
Varietal thiols; Precursors; 3MH; UPLC-MS/MS; SIDA method
Funding
- AEB
- ANRT (CIFRE) [2015/0690]
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Varietal thiols are key aroma compounds in wine issued from multiple and complex origins. Several precursor families have been identified in grapes and must and have been widely studied. But a large part of thiol origin still remains unknown. Thus, we only have an incomplete picture of thiol precursors and there is a lack of knowledge on pre-fermentative mechanisms that can impact their levels. Our study focused on the formal identification and the quantification of new varietal thiol precursors in must. First of all, we synthesized natural and labeled standards using an original multi-step strategy, then we developed and validated a UPLC-MS/MS method that allowed us to identify and quantify for the first time a dipeptide S-conjugate to 3MH, the gamma GluCys-3MH, in Sauvignon B. We observed the S-4-mercapto-4-methylpentan-2-one-L-cysteinyl-glycine (CysGly-4MMP) and S-4-mercapto-4-methylpentan-2-one-N-(L-gamma-glutamyl)-L-cysteine (gamma GluCys-4MMP) but at too low concentration to be quantified. (C) 2017 Elsevier Ltd. All rights reserved.
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