4.6 Article

The optical shielding performances and mechanisms of green flame-retardant two-component matte films under various application conditions

Journal

RSC ADVANCES
Volume 11, Issue 21, Pages 12696-12702

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra01266e

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Funding

  1. National Natural Science Foundation of China [51905295]
  2. National Key Research and Development Program of China [2016YFC0204400]

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By adjusting environmental factors and adding nanoparticles, the coating achieved excellent shielding performance for ultraviolet light, with TiO2 nanoparticles playing a positive role in delaying the thermal decomposition process during flame retardance.
Herein, we meticulously investigated the optical shielding performances and mechanisms of green flame-retardant two-component waterborne polyurethane matte films based on a previous study. The relevant performances were evaluated by changing various environmental factors including nanoparticle content, pH, temperature and storage-time. Specifically, upon combination with TiO2, the ultraviolet-light transmittance was reduced to 1.9% and the 60 degrees glossiness decreased by 63%. When the pH was 8.0, the shielding efficiency and transmittance of ultraviolet light were 100% and 0%, respectively. The 60 degrees glossiness of spin-films increased with an increase in storage time. Besides, TiO2 nanoparticles were beneficial for delaying the thermal decomposition via synergistic flame retardance.

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