4.8 Review

Anderson-type polyoxometalates: from structures to functions

Journal

NANOSCALE
Volume 13, Issue 15, Pages 7119-7133

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nr00397f

Keywords

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Funding

  1. National Natural Science Foundation of China [21271068, 21401050]
  2. Natural Science Foundation of Hubei Province [2015CFA131]
  3. Wuhan Applied Basic Research Program [2014010101010020]

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Anderson-type polyoxometalates have made significant progress in the past decade and have shown unique charm in multiple fields. Their highly flexible topological structure and diverse functionalization methods make them ideal platforms for rational design and controllable synthesis.
Anderson-type polyoxometalates (POMs) are one of the most important groups of the POM family. In the past decade, the functionalization of Anderson-type POMs has achieved significant progress and these materials have already shown unique charm in catalysis, molecular devices, energy materials, and inorganic biochemical drugs. In particular, their highly flexible topological structure and diverse functionalization methods make them the most convenient and universal platforms for rational design and controllable synthesis. This review provides a deep discussion on the recent progress in the synthetic methodology, structural exploration, and promising applications of Anderson-type POMs. It also summarizes the latest research directions and provides future prospects.

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