Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 39, Pages 4787-4790Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01484f
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Funding
- National Natural Science Foundation of China [21871080]
- Shanghai Leading Academic Discipline Project [B502]
- Shanghai local government
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A novel free radical-initiated reaction between cyclic ethers and maleimide iodides through C-H activation has been developed, providing a simple approach to derive cyclic ethers without using transition metallic catalysts. These cyclic ethers can be further applied in various cross coupling reactions.
Cyclic ethers are important scaffolds employed in the synthesis of various natural products and pharmaceutical ingredients. A novel free radical-initiated reaction between cyclic ethers and maleimide iodides through C-H activation is developed, avoiding the use of transition metallic catalysts. This method provides a simple approach to derive cyclic ethers, which were further applied in various cross coupling reactions.
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