4.7 Review

Recent advances in annulation reactions based on zwitterionic π-allyl palladium and propargyl palladium complexes

Journal

ORGANIC CHEMISTRY FRONTIERS
Volume 8, Issue 13, Pages 3475-3501

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00273b

Keywords

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Funding

  1. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
  2. National Natural Science Foundation of China [21372250, 21121062, 21302203, 20732008, 21772037, 21772226, 21861132014, 91956115]
  3. Fundamental Research Funds for the Central Universities [222201717003]

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In recent years, Pd-catalyzed annulation reactions using zwitterionic pi-allyl palladium intermediates have been extensively studied, demonstrating their importance in the synthesis of carbocyclic and heterocyclic compounds with potential pharmaceutical and biological applications. This review highlights the significant advances in organic synthesis based on zwitterionic pi-allyl palladium and propargyl palladium.
In the past few years, Pd-catalyzed annulation reactions through zwitterionic pi-allyl palladium intermediates have been extensively investigated. Meanwhile, zwitterionic pi-allyl palladium and propargyl palladium have also been successfully demonstrated to be a vital and versatile synthon for the construction of carbocyclic and heterocyclic compounds, which include both structural scaffolds used in the pharmaceutical industry and novel heterocyclic skeletons with potential biological appeal. This review highlights representative advances in organic synthesis based on zwitterionic pi-allyl palladium and propargyl palladium.

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