4.6 Article

An easily obtained hypercrosslinked pyrene-based porous organic polymer as a high performance electrode material for lithium-ion batteries

Journal

NEW JOURNAL OF CHEMISTRY
Volume 45, Issue 16, Pages 7060-7064

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj00089f

Keywords

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Funding

  1. Science and Technology Commission of Shanghai Municipality [19DZ2271100]
  2. Program for Professor of Special Appointment (Eastern Scholar) at the Shanghai Institutions of Higher Learning
  3. National Natural Science Foundation of China [21805134]
  4. Natural Science Foundation of Jiangsu Province, China [BK20191363]
  5. Science and Technology Innovation Project for Overseas Students from Nanjing City
  6. NJTECH [39837141]

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HcPPy, a robust hypercrosslinked pyrene-based porous organic polymer, was effectively achieved through a one-step reaction and demonstrated as an excellent electrode material for both anode and cathode applications in lithium ion batteries. It exhibited high capacity at high current densities as an anode material and good rate and cycling stability as a cathode material.
Through one-step reaction, a robust hypercrosslinked pyrene-based porous organic polymer (HcPPy) with a high BET surface area was effectively achieved from pyrene. HcPPy was demonstrated as an excellent electrode material. When explored as an anode material for lithium ion batteries, HcPPy exhibited a high capacity even at high current densities (up to 683 mA h g(-1) at 1000 mA g(-1)). When used as a cathode material, HcPPy exhibited good rate and cycling stability with a capacity of 110 mA h g(-1) at 100 mA g(-1) over 200 cycles.

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