Journal
DALTON TRANSACTIONS
Volume 50, Issue 18, Pages 6003-6033Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt00749a
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Funding
- Russian Science Foundation [16-13-10064]
- Academy of Finland [317903]
- Academy of Finland Flagship Programme, Photonics Research and Innovation (PREIN) [320166]
- Academy of Finland (AKA) [317903] Funding Source: Academy of Finland (AKA)
- Russian Science Foundation [19-13-13006] Funding Source: Russian Science Foundation
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This work explores di- and polynuclear complexes of +1 oxidation state metal ions (M = Cu, Ag, Au) and their photophysical properties, focusing on the impact of phosphine bridging ligands, their flexibility, and denticity.
Copper subgroup metal ions in the +1 oxidation state are classical candidates for aggregation via non-covalent metal-metal interactions, which are supported by a number of bridging ligands. The bridging phosphines, soft donors with a relatively labile coordination to coinage metals, serve as convenient and essential components of the ligand environment that allow for efficient self-assembly of discrete polynuclear aggregates. Simultaneously, accessible and rich modification of the organic spacer of such P-donors has been used to generate many fascinating structures with attractive photoluminescent behavior. In this work we consider the development of di- and polynuclear complexes of M(i) (M = Cu, Ag, Au) and their photophysical properties, focusing on the effect of phosphine bridging ligands, their flexibility and denticity.
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