Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 40, Pages 4958-4961Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc08411e
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Funding
- NASA [NNX16AD27G]
- W. M. Keck Foundation
- Alexander von Humboldt Foundation (Feodor Lynen research fellowship)
- NASA [906853, NNX16AD27G] Funding Source: Federal RePORTER
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The first formation of phosphine imide and its isomer phosphinous amide was achieved by exposing phosphine and ammonia ices to ionizing radiation. This method can be used to prepare, separate, and detect highly reactive compounds like intermediates of Wittig reactions.
We present the first formation of the previously elusive phosphine imide (HN PH3) along with its phosphinous amide (H2N-PH2) isomer via exposure of phosphine (PH3) and ammonia (NH3) ices to ionizing radiation. Our approach may be extended to prepare, separate, and detect highly reactive compounds such as intermediates of Wittig reactions.
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