Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 30, Pages 3688-3691Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc00306b
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An efficient and selective benzylic C(sp(3))-H addition of o-CH3-substituted tertiary aromatic amines to alkenes has been achieved using a scandium catalyst supported by an anilido-oxazoline ligand, providing an atom-economic method for the synthesis of a new family of alkylated tertiary anilines. A wide range of amine and alkene substrates are compatible with the catalyst system.
An efficient and selective benzylic C(sp(3))-H addition of o-CH3-substituted tertiary aromatic amines to alkenes has been achieved using an anilido-oxazoline ligand supported scandium catalyst, which provides an atom-economic method for the synthesis of a new family of alkylated tertiary anilines. A wide range of amine and alkene substrates are compatible with the catalyst system.
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