Journal
DALTON TRANSACTIONS
Volume 50, Issue 19, Pages 6667-6672Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt00601k
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- Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy [DE-AC02-05CH11231, 6878940]
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The new bifunctional salts were prepared from the phosphorus(v)-containing chelating ligand H-2-DPN and characterized using various spectroscopic techniques. Both H-2-DPN and Li[B(DPN)(2)] were structurally characterized by X-ray crystallographic methods. These salts are related to materials being examined for use in electrolyte solutions for lithium-ion battery (LIB) applications.
Several new bifunctional salts, Li[B(DPN)(2)], Li[B(DPN)(ox)] and Li[P(DPN)(3)], have been prepared from the phosphorus(v)-containing chelating ligand 2,3-dihydroxynaphthalene-1,4-(tetraethyl)bis(phosphonate) (H-2-DPN). The new lithium salts were characterized by a variety of spectroscopic techniques. Both H-2-DPN and Li[B(DPN)(2)] have been structurally characterized by X-ray crystallographic methods. These salts are related to materials being examined for use in electrolyte solutions for lithium-ion battery (LIB) applications.
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