4.8 Article

High electrical conductivity and breakdown current density of individual monolayer Ti3C2Tx MXene flakes

Journal

MATTER
Volume 4, Issue 4, Pages 1413-1427

Publisher

CELL PRESS
DOI: 10.1016/j.matt.2021.01.021

Keywords

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Funding

  1. Nebraska Public Power District through the Nebraska Center for Energy Sciences Research (NCESR)
  2. National Science Foundation (NSF) through the Nebraska Materials Research Science and Engineering Center (MRSEC) [DMR-1420645]
  3. NSF [ECCS-1542182, DMR-1740795]
  4. Nebraska Research Initiative

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This study reports the high breakdown current density in Ti3C2Tx MXene and demonstrates its high electrical conductivity and electron mobility, making it suitable for nanometer-thin interconnects. The breakdown current density of this material is comparable to other two-dimensional materials, highlighting its potential for future applications.
As the scaling down of integrated circuits continues, there is a growing interest in electrically conductive materials with high current-carrying capacity for next-generation on-chip interconnects. Here, we report very high breakdown current density in Ti3C2Tx MXene, an emerging two-dimensional material. We performed electrical measurements of individual high-quality monolayer Ti3C2Tx flakes, which were prepared by an improved synthesis method, and found that they exhibit electrical conductivities of up to 11,000 S cm(-1) and field-effect electron mobilities of up to 6 cm(2) V-1 s(-1), both representing the best values reported for Ti3C2Tx flakes so far. All flakes exhibited very similar breakdown current densities of about 1.2 x 10(8) A cm(2), which are comparable with the best two-dimensional materials, including graphene, The remarkable combination of high electrical conductivity and high current-carrying capacity makes Ti3C2Tx promising for nanometer-thin interconnects and warrants investigation of breakdown current densities of other materials from the large MXene family.

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