Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 45, Pages 5586-5589Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01319j
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Funding
- National Natural Science Foundation of China [92061201, 21825106, 21801228]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
- Zhengzhou University
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In this study, a 54-nuclei copper nanocluster, Cu-54, was reported as the largest atom-precise Cu-I/Cu-II mix-valent cluster. The Cu-54 nanoclusters supported by TiO2 showed decent photocatalytic activity for phenol degradation under visible light. This work provides a platform to explore the catalytic behaviors of Cu-I/Cu-II nanosystems.
Herein, we report a 54-nuclei copper nanocluster, [Cu54S13O6((BuS)-Bu-t)(20)((BuSO3)-Bu-t)(12)] (Cu-54), which is the largest atom-precise Cu-I/Cu-II mix-valent cluster reported. The Cu-54 nanoclusters supported by TiO2 exhibit decent photocatalytic activity for phenol degradation under visible light. This work provides a platform to explore the catalytic behaviors of Cu-I/Cu-II nanosystems.
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