A water stable Eu(iii)-organic framework as a recyclable multi-responsive luminescent sensor for efficient detection of p-aminophenol in simulated urine, and MnVII and CrVI anions in aqueous solutions

A novel 3D Eu(iii) metal-organic framework (Eu-MOF-1) formulated as [Eu(L)(H2O)(DMA)] (L = 2-(2-nitro-4-carboxylphenyl)terephthalic acid) has been successfully synthesized under solvothermal conditions and characterized by structural analyses. Eu-MOF-1 displays a new 3D framework containing Eu-III ions, ligand L, and coordinated DMA molecules and water molecules. The fluorescence investigations indicate that Eu-MOF-1 emits bright red luminescence, and shows relatively high water stability and outstanding chemical stability under a relatively wide range of pH conditions. It is noteworthy that Eu-MOF-1 can quantitatively detect p-aminophenol (PAP) which is a metabolite of phenylamine in human urine. More significantly, Eu-MOF-1 is the first reported multi-responsive luminescent sensor for detecting the biomarker PAP, and Mn-VII and Cr-VI anions with high selectivity, sensitivity, recyclability and relatively low detection limits in aqueous solutions. Furthermore, the possible sensing mechanisms of Eu-MOF-1 for selective sensing have also been explored in detail. Eu-MOF-1 could be an ideal candidate as a multi-responsive luminescent sensor in biological and environmental areas.

Automated summary

Eu-MOF-1 is a novel 3D Eu(iii) metal-organic framework with bright red luminescence, high water and chemical stability, and the ability to quantitatively detect PAP. It is a multi-responsive luminescent sensor with high selectivity and sensitivity for detecting biomarkers and certain anions in aqueous solutions, making it an ideal candidate for biological and environmental applications.