Journal
CRYSTENGCOMM
Volume 23, Issue 34, Pages 5753-5757Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ce00464f
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Funding
- National Natural Science Foundation of China [21671040, 21773029]
- Natural Science Fund of Fujian Province [2020J01438]
- open fund of State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
- City University of Hongkong
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Two isomeric zeolite-like metal-organic frameworks were successfully prepared, showing rare isomeric characteristics. One of the frameworks exhibited mechanically responsive luminescence emission after grinding, with permanent porosity and selective CO2 adsorption capabilities.
Two isomeric zeolite-like metal-organic frameworks with the formula of [(CH3)(2)NH2][Cd(TPO)]center dot xsolvent were successfully prepared and characterized. Both frameworks are constructed from tetrahedral TPO3- nodes and tetrahedrally connected Cd2+ nodes, representing rare examples of zeolite-like MOFs with an isomeric characteristic. Moreover, one of the frameworks shows mechanically responsive luminescence emission after the crystals are ground for different times. Additionally, it has permanent porosity, and can selectively adsorb CO2 over N-2.
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