Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 8, Issue 14, Pages 3770-3775Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00276g
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Funding
- National Natural Science Foundation of China [21971066, 21772042]
- Science and Technology Commission of Shanghai Municipality [18JC1412300]
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A novel iron-catalyzed chemo- and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds is presented, where an iron porphyrin exhibits specific catalytic activity, distinct from commonly used precious metal catalysts.
Herein we present a novel iron-catalyzed chemo- and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.
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