High-temperature electron transfer coupled spin transition (ETCST) with hysteresis in a discrete [Fe2Co2] Prussian blue analogue

A thermoresponsive Fe-Co based discrete Prussian blue analogue (PBA) with the general formula [Fe(Tp)(CN)(3)](2)[Co{en(Bn)py}](2)(ClO4)(2)center dot 4MeOH center dot 4H(2)O i.e. [1.4MeOH center dot 4H(2)O] is reported, which discloses a sharp and high temperature ETCST along with a wide hysteresis of 10 K observed for its desolvated complex 1.

Automated summary

A thermoresponsive Fe-Co based discrete Prussian blue analogue has been reported, showing a sharp and high temperature ETCST along with a wide hysteresis of 10 K observed for its desolvated complex 1.