4.7 Article

A hydrogen evolution catalyst lowering energy consumption in aluminum anodization

Journal

INORGANIC CHEMISTRY FRONTIERS
Volume 8, Issue 13, Pages 3284-3291

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qi00377a

Keywords

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Funding

  1. National Natural Science Foundation of China [51777152]
  2. Natural Science Foundation of Shaanxi Province [2019JLZ-09, 2021JZ-01]
  3. Fundamental Research Funds for the Central Universities [XJJ2018055]

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The study introduced NCNTs/Pt electrodes as cathodes in aluminum anodization, showing promising results in reducing energy consumption and improving efficiency. This novel approach of utilizing carbon-based noble metals as efficient catalysts offers a new pathway for energy conservation in the process.
Aluminum anodization process requires a lot of electrical energy for the migration of ions in a barrier-type oxide film, in which electrode polarization leads to massive energy consumption. The cathodes are considered to be modified with catalysts, reducing their hydrogen evolution reaction (HER) overpotential in order to improve its energy utilization efficiency. In this study, N-doped carbon nanotube (NCNT)-supported Pt nanoparticle (NCNTs/Pt) electrodes were prepared instead of the traditional stainless steel cathodes. Considering the neutral electrolyte used for the aluminum anodizing process, the NCNTs/Pt electrodes were tested in an ammonium adipate (pH = 6.8), exhibiting an overpotential of 125 mV at -10 mA cm(-2) and a mass activity of 107.6 A g(Pt)(-1). The NCNTs/Pt electrodes were employed as cathodes to measure the aluminum anodization energy consumption, which enabled 9.04% reduction at a formation voltage of 150 V compared with stainless steel electrodes. This study provides a way for energy conservation in the aluminum anodization process, with the novel pathway altering the cathodic electrode using carbon-based noble metals as efficient catalysts.

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