Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 19, Issue 23, Pages 5028-5047Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob00506e
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Korea government (MSIT) [2012M3A7B4049644, 2020R1A6A1A06046728, 2021R1A5A6002803, 2021R1A2C1003135]
- Nano.Material Technology Department Program through the National Research Foundation of Korea (NRF) - Korea government (MSIT) [2012M3A7B4049644, 2020R1A6A1A06046728, 2021R1A5A6002803, 2021R1A2C1003135]
- National Research Foundation of Korea [2021R1A2C1003135] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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This review provides a brief overview of recent progress in transition-metal-catalyzed direct ortho-selective C-H functionalization of free phenols, which is of great importance in synthetic research.
Phenols are important readily available chemical feedstocks and versatile synthetic building blocks for diverse synthetic transformations. Their motifs are prevalent in a diverse array of natural products, pharmaceuticals, functional materials, and privileged chiral ligands. Consequently, the development of facile and direct site-selective C-H bond functionalization of free phenols is of great importance and considerable interest to both industry and academic research. Over the past decades, transition-metal-catalyzed C-H bond functionalization has become as a powerful synthetic tool in organic synthesis. In this review, we provide a brief overview of recent progress in the transition-metal-catalyzed direct ortho-selective C-H functionalization of free phenols.
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