4.7 Article

BODIPY-vinyl dibromides as triplet sensitisers for photodynamic therapy and triplet-triplet annihilation upconversion

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 49, Pages 6039-6042

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01881g

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The new generation of halogen-based triplet sensitisers were developed by incorporating geminal dibromides into the pi-conjugation of BODIPY, enhancing intersystem crossing and excited triplet states.
We devised a new generation of halogen-based triplet sensitisers comprising geminal dibromides at the vinyl backbone of a BODIPY fluorophore. Incorporating geminal dibromides into the pi-conjugation of BODIPY enhanced intersystem crossing due to the heavy atom effect, which in turn improved the extent of excited triplet states.

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