4.6 Article

A nickel-catalyzed silylation reaction of alkyl aryl sulfoxides with silylzinc reagents

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 19, Issue 23, Pages 5082-5086

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob00840d

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Funding

  1. National Basic Research Program of China [2015CB856600]

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The Ni(PEt3)Cl-2-catalyzed silylation of alkyl aryl sulfoxides with silylzinc reagents allows for the conversion to arylsilicon compounds under mild reaction conditions, with tolerance to a variety of functional groups and a wide scope of substrates.
Ni(PEt3)Cl-2-catalyzed silylation of alkyl aryl sulfoxides with silylzinc reagents was carried out. This protocol allows alkyl aryl sulfoxides to convert to arylsilicon compounds under mild reaction conditions, tolerates a range of functional groups and is suitable for a wide scope of substrates.

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