Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 8, Issue 9, Pages 1991-1996Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00169h
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Funding
- National Natural Science Foundation of China [21772046, 2193103, 22001038]
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Organoboron compounds have diverse transformations of C-B bonds, and their synthetic application value can be greatly increased by introducing easy-to-transform functional groups. The first synthesis of sp(2)-alpha-haloboronates via an in situ alpha-sp(3)-boron radical intermediate proves their high synthetic application value.
Organoboron compounds play an important role in various fields due to the diverse transformations of C-B bonds. The introduction of easy-to-transform functional groups into organoboron compounds would greatly increase their synthetic application value. This article reports the first synthesis of sp(2)-alpha-haloboronates via an in situ alpha-sp(3)-boron radical intermediate, and proved their high synthetic application value through subsequent transformations.
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