Journal
RSC ADVANCES
Volume 11, Issue 22, Pages 13497-13512Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra01405f
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Three newly synthesized hydrazide derivatives showed high inhibition efficiencies on the corrosion of C-steel in 1 M HCl, forming a protective layer on the surface. The adsorption of these compounds followed the Temkin adsorption isotherm and they belonged to mixed-type inhibitors according to polarization curves. Molecular simulation methods further confirmed the inhibitory effect of hydrazide derivatives at the molecular level.
The corrosion inhibition of C-steel in 1 M HCl was assessed using three newly synthesized hydrazide derivatives (H1, H2 and H3) using weight loss (WL), potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques. Also, the adsorption of these compounds was confirmed using several techniques such as atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). High inhibition efficiencies were obtained resulting from the constitution of the protective layer on the C-steel surface, which increased with increasing concentration and temperature and reached 91.7 to 96.5% as obtained from the chemical method at 20 x 10(-6) M at 45 degrees C. The polarization curves refer to these derivatives belonging to mixed-type inhibitors. The adsorption of (H1, H2 and H3)on the CS surface follows the Temkin adsorption isotherm. Inhibition influence of hydrazide derivatives at the molecular level was greatly proven using quantum chemical calculations and Monte Carlo simulation methods. Furthermore, the molecular simulation results evidenced the adsorption of these derivatives on the carbon steel surface.
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