Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 50, Pages 6193-6196Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01863a
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Funding
- German Science Foundation
- RWTH Aachen Foundation
- Fonds der Chemischen Industrie
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A site-selective direct arylation reaction of carbazole and other N-heterocycles with diazo-naphthalen-2(1H)-ones has been developed, showing the potential for selective C3-arylation with Au(i)-NHC catalysts and selective N-H arylation with palladium acetate. The applicability of these arylation reactions was demonstrated through one-pot, two-fold diarylation reactions of carbazole.
A site-selective direct arylation reaction of carbazole and other N-heterocycles with diazo-naphthalen-2(1H)-ones has been developed. While Au(i)-NHC catalysts lead to selective C3-arylation, palladium acetate allows for selective N-H arylation, displaying complete site-selectivity each. To show the applicability of these arylation reactions, one-pot, two-fold diarylation reactions of carbazole were demonstrated.
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