Studies on structural, dielectric and optical properties of (Ba0.95Ca0.05)1-x(Ti0.8Sn0.2)1-xNaxNbxO3 lead-free ceramics

(Ba0.95Ca0.05)(1-x)(Ti0.8Sn0.2)(1-x)NaxNbxO3 (BCNTSNO3) lead-free ceramics with compositions (x = 0.75, 0.8 and 0.85) were synthesized through the traditional solid-state reaction method. X-ray powder diffraction analysis showed the formation of a single phase compound crystallized in tetragonal space group P4mm. The evolution of Raman spectra displayed a disorder introduced into the structure, which favors a ferroelectric relaxor behavior. The dependence of the dielectric properties on temperature exhibited two composition ranges with different behaviors. Ferroelectric relaxor properties were observed for the compositions x < 0.85 and the classical ferroelectric behavior for x = 0.85. Lead free (Ba0.95Ca0.05)(1-x)(Ti0.8Sn0.2)(1-x)NaxNbxO3 ceramics exhibited larger dielectric constants than those of parent crystal NaNbO3, suggesting that it is a good candidate for lead-free ceramics in several industrial applications. Using UV-Vis spectroscopy, the optical band gap energy of ceramics (Ba0.95Ca0.05)(1-x) (Ti0.8Sn0.2)(1-x)NaxNbxO3 is found at 2.89, 2.92, and 3.05 eV for x = 0.75, 0.8 and 0.85, respectively.

Automated summary

Lead-free ceramics BCNTSNO3 were synthesized through a traditional method, exhibiting good dielectric and optical properties. XRD and Raman analysis showed ferroelectric relaxor or classical ferroelectric behaviors, making BCNTSNO3 suitable for industrial applications. UV-Vis spectroscopy revealed the optical band gap energy for BCNTSNO3 with different compositions.