Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 8, Issue 15, Pages 4112-4117Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00591j
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Funding
- NSFC [21772208, 22001226, 21633013]
- NSFC of Jiangsu Province [BK20201183]
- Key Research Program of Frontier Sciences of CAS [QYZDJSSW-SLH051]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [20KJB150016]
- Yancheng Institute of Technology [xjr2019032]
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A efficient [3 + 1 + 1] cyclization of vinyl oxiranes has been developed for the synthesis of oxazolidinones via tandem palladium catalysis. This reaction provides an atom- and step-efficient strategy to produce oxazolidinones from readily available azides and carbon monoxide under mild additive- and base-free conditions. Mechanistic studies demonstrated that the reaction occurred through an in situ generated isocyanate intermediate.
An efficient [3 + 1 + 1] cyclization of vinyl oxiranes for the synthesis of oxazolidinones has been developed via tandem palladium catalysis. This reaction provides an atom- and step-efficient strategy to produce oxazolidinones from readily available azides and carbon monoxide under mild additive- and base-free conditions. The mechanistic studies showed that the reaction occurred through an in situ generated isocyanate intermediate.
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