Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 23, Issue 24, Pages 13434-13439Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp00659b
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Funding
- Australian Research Council [DP170104477]
- NSF [CHE-1807486]
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NDIs are shown to spontaneously arrange with CB[8] in an aqueous environment through purely non-covalent interactions, resulting in a highly fluorescent 2 : 2 supramolecular complex. The increased fluorescence is attributed to the formation of NDI-NDI excimers within the supramolecular complex.
Naphthalene diimides (NDIs) are shown to arrange spontaneously co-facially with cucurbit[8]uril (CB[8]) in an aqueous environment through purely non-covalent interactions. The resultant 2 : 2 supramolecular complex of NDI and CB[8] is highly fluorescent (>30 times more than the constituent NDIs) due to the formation of NDI-NDI excimers within the supramolecular complex.
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