Journal
NEW JOURNAL OF CHEMISTRY
Volume 45, Issue 26, Pages 11737-11751Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj00503k
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Funding
- Iran National Science Foundation (INSF)
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The study investigated the impact of two different substrates on improving capacities of SnCoS4 nanoparticles in lithium-ion batteries. The results showed that the P-PNT-SnCoS4 structure had the highest reversible capacity of 784 mA h g(-1) at a current density of 0.2 A g(-1) after 200 cycles. This demonstrates the potential of using binary metal sulfides supported by 3D polymer-based substrates as promising anode materials in future LIBs.
In the current study, the impact of two different substrates was investigated on the improvement in capacities. SnCoS4 nanoparticles were coated on polypyrrole nanotubes (PNT) and pyrolyzed polypyrrole nanotubes (P-PNT) using the facile hydrothermal method. Both anode materials were electrochemically compared to pure nanoparticles in the lithium-ion half-cell. The results of electrochemical analysis introduced the P-PNT-SnCoS4 as an optimum structure with a reversible capacity of 784 mA h g(-1) at a current density of 0.2 A g(-1) after 200 cycles. This finely-crystallized nanoparticle supported by carbonaceous polypyrrole nanotubes still maintained its capacity (424 mA h g(-1)) at a higher current density of 4 A g(-1), which shows the efficient synergistic contribution of the substrate to buffering the volume changes in Sn-based anodes. We can conclude that binary metal sulfides supported by 3D polymer-based substrates have great potential for application as promising anode materials in future lithium-ion batteries (LIBs).
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