4.7 Review

Recent advances on electrocatalytic fixation of nitrogen under ambient conditions

Related references

Note: Only part of the references are listed.
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Summary: Electrochemical nitrogen reduction reaction has the potential to be an alternative to the industrial Haber-Bosch process for NH3 production due to its low energy consumption and environment friendliness. Iron-group materials show promise as non-noble metal electrocatalysts with cost and performance advantages, but further strategies are needed to improve efficiency and selectivity.

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Summary: The study introduces the use of sputtered TiB2 film for efficient artificial N2 reduction electrocatalysis, achieving high NH3 yield and Faradaic efficiency in HCl solution with excellent durability. This is attributed to the positively charged Ti atomic plane, as evidenced by density functional theory calculations, which facilitates N2 molecules adsorption, activation, and hydrogenation while suppressing the binding of H atoms.

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A magnetron sputtered Mo3Si thin film: an efficient electrocatalyst for N2 reduction under ambient conditions

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Summary: This study reports the electrocatalytic properties of a Mo3Si thin film sputtered on graphite paper for NH3 synthesis, showing high NH3 yield rate and Faraday efficiency, as well as demonstrating excellent stability and selectivity. The synergy of metallic conductivity of Mo3Si and high chemical activity of exposed Mo ions benefits N-2 adsorption and activation, ultimately leading to NH3 production.

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