Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 19, Issue 27, Pages 6085-6091Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ob00144b
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- DST, New Delhi
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A chiral Cu(i)-bisoxazoline complex was used to catalyze the enantioselective electrophilic fluorination of 3-indolinone-2-carboxylates with NFSI, resulting in the production of chiral 2-fluoro-3-indolinone-2-carboxylates in good yields with excellent enantioselectivities. This marks the first report of enantioselective fluorination of 2-substituted 3-indolinones using a chiral Cu(i)-bisoxazoline complex.
A chiral Cu(i)-bisoxazoline complex catalyzed enantioselective electrophilic fluorination of 3-indolinone-2-carboxylates with NFSI has been accomplished to produce chiral 2-fluoro-3-indolinone-2-carboxylates in good yields with excellent enantioselectivities. This is the first report on the enantioselective fluorination of 2-substituted 3-indolinones using a chiral Cu(i)-bisoxazoline complex.
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