4.7 Article

Effect of phosphogypsum on saline-alkalinity and aggregate stability of bauxite residue

Journal

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume 31, Issue 5, Pages 1484-1495

Publisher

ELSEVIER
DOI: 10.1016/S1003-6326(21)65592-9

Keywords

bauxite residue; phosphogypsum; saline-alkalinity; aggregate stability

Funding

  1. National Natural Science Foundation of China [42030711, 41877511]

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The study found that phosphogypsum treatment significantly altered the saline-alkalinity of bauxite residue and improved its aggregate stability, providing an effective approach for reclaiming bauxite residue disposal areas.
A column experiment was conducted to investigate the effect of phosphogypsum (PG) on the saline-alkalinity, and aggregate stability of bauxite residue. Results showed that: with increasing leaching time, the concentrations of saline-alkali ions decreased while the SO42- concentration increased in bauxite residue leachate; compared with CK (control group) treatment, pH, electric conductivity (EC), exchangeable sodium percentage (ESP), sodium absorption ratio (SAR), and exchangeable Na+ content of bauxite residue were reduced following PG treatment; average particle sizes in aggregates following CK and PG treatments were determined to be 155 and 193 nm, respectively. SR-mu CT test results also confirmed that bauxite residue following PG treatment acquired larger aggregates and larger pore diameter. These results indicate that the PG treatment could significantly modulate the saline-alkalinity, and simultaneously enhance aggregate stability of bauxite residue, which provides a facile approach to reclaim bauxite residue disposal areas.

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