Journal
NEW JOURNAL OF CHEMISTRY
Volume 45, Issue 27, Pages 12159-12167Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj02499j
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Funding
- Ministry of Science and Higher Education of the Russian Federation
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Carborane maleimides were synthesized with good yields through thermal cyclization of maleamic acids prepared from the reaction of 3-amino-o-carborane with maleic or 3-bromomaleic anhydrides. The selective reactivity of synthesized maleimides towards S-nucleophiles was demonstrated, leading to the development of potential candidates for biological applications or new materials with variation in substitution patterns.
Carborane maleimides were prepared in good yields through the thermal cyclization of maleamic acids prepared by the reaction of 3-amino-o-carborane with maleic or 3-bromomaleic anhydrides, respectively. The selective reactivity of synthesized maleimides towards S-nucleophiles was demonstrated. As a result a series of boronated thiosuccinimide- or thiomaleimide-substituted compounds including boron rich ones was obtained and fully characterized. Furthermore the opportunity of variation with substitution patterns may lead to the development of potential candidates for biological applications or the development of new materials.
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