Pyrolysis of corn cob: physico-chemical characterization, thermal decomposition behavior and kinetic analysis

Bioenergy out of lignocellulosic biomass, especially from agricultural crop residues, is making massive inroads in our quest for sustainable environment. In the present study, detailed physico-chemical characterization, thermal degradation characteristics, and kinetics of pyrolysis of corn cob are reported. Thermogravimetric experiments were performed at different heating rates, such as, 10, 20, and 30 degrees C/min in an inert atmosphere. Thermogravimetric (TG) and derivative thermogravimetric (DTG) curves inferred the thermal behavior characteristics of corn cob. Significant content of cellulose and hemicellulose put together (76.23%) suggested tremendous potential of corn cob to give enhanced yield of bio-oil through pyrolysis. Maximum mass loss of 61.92% for corn cob was observed in the temperature range of 180-360 degrees C. The kinetic parameters for pyrolysis of corn cob were determined by employing model-free isoconversional methods like, Kissinger-Akahira-Sunose, Flynn-Wall-Ozawa, and Starink. Activation energy from FWO (62.44 kJ/mol) and Starink (61.74 kJ/mol) method for pyrolysis of corn cob was found to be in close proximity. The results revealed prospective bioenergy potential of corn cob as a feedstock for pyrolysis process.

Automated summary

The study focuses on the bioenergy potential of corn cob, analyzing its physico-chemical characteristics, thermal degradation behavior, and pyrolysis kinetics. Results suggest significant content of cellulose and hemicellulose in corn cob, indicating its high yield potential for bio-oil production through pyrolysis. The activation energy for pyrolysis of corn cob, determined using isoconversional methods, was found to be in close proximity, highlighting the prospective bioenergy potential of corn cob as a feedstock for the pyrolysis process.