Ionic conductivity and dielectric properties of bulk SPP-PEG hydrogels as Na+ ion-based SPE materials for energy storage applications

In this work, a green SPP-PEG hydrogel material, containing Na+ ions, was synthesized by a green chemistry method using sodium polyphosphate and polyethylene glycol in water. This hydrogel has an amorphous morphology and a sandwiched matrix with a floating layer, which allows ions to move easily inside the matrix. Flexibility and sticky nature are the key properties that enable forming a good interface on the electrode surface. The hydrogel tends to change to the plasma phase above 70 degrees C. A Na+ ion-based hydrogel electrolyte shows a stability window of 2.75 volts with >96% ionic nature of conductivity in the order of 10(-4) S cm(-1) with a diffusivity constant in the order of 10(-9) m(2) s(-1) and mobility in the order of 10(-7) m(2) V-1 s(-1) at room temperature. The hydrogel matrix shows cage-type hopping with a value of power exponent >1 at lower temperatures, and the activation energy of ionic movement was observed to be quite low, i.e. 0.488 eV. Dielectric properties of the hydrogel show a high amount of capacitance with negligible electrode contribution. Regarding temperature dependence, this study confirms that conductivity and matrix relaxation are independent of time and temperature.

Automated summary

The green SPP-PEG hydrogel material with Na+ ions synthesized in this study demonstrated high ionic conductivity and excellent stability at room temperature.