Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 59, Pages 7256-7259Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc02293h
Keywords
-
Categories
Ask authors/readers for more resources
The stereospecific synthesis of helicenoid-based phosphepines and chiral P-containing polycyclic aromatic hydrocarbons is presented, with investigation into the impact of molecular design on structure, (chir)optical properties (including circularly polarized luminescence), and redox properties. An axial to central chirality transfer from the BINAP moiety to the P-atom is observed in these systems.
We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available