4.7 Article

Controlling the molecular arrangement of racemates through weak interactions: the synergy between π-interactions and halogen bonds

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 60, Pages 7366-7369

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01700d

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Halogen bonds and pi-stacking interactions lead to the sorting of pi-extended R- and S-isomers, with a positive synergistic effect between the pi-interactions and the halogen bonds being the origin of such phenomena. As a result, enantiomeric building blocks form homoleptically connected quadrangular structures.
POMIDLINE HORIZONTAL ELLIPSISX and NMIDLINE HORIZONTAL ELLIPSISX halogen bonds in combination with pi-stacking interactions lead to the sorting of pi-extended R- and S-isomers. Theoretical calculations point to a positive synergistic effect between the pi-interactions and the halogen bonds to be the origin of such phenomena. As a result, enantiomeric building blocks form homoleptically connected quadrangular structures.

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