Journal
DALTON TRANSACTIONS
Volume 50, Issue 31, Pages 10674-10688Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt01955d
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Funding
- BRNS
- SERB (India)
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This article highlights the recent developments in silylene-coinage metal chemistry, focusing on synthetic approaches, unusual properties, and catalytic efficiency of these complexes. Further research is needed to explore the potential of silylene-coinage metal complexes in various chemical reactions.
This article intends to highlight and comprehensively summarize the recent developments in the field of silylene-coinage metal chemistry. Recent years have witnessed exponential growth in the utilization of N-heterocyclic silylenes as ligands in transition metal chemistry. Still, silylene-coinage metal complexes have only started to appear very recently. Particular attention is focused on the synthetic approaches to silylene-coinage metal complexes and their unusual properties derived from the spectroscopic and crystallographic data. Recent studies have demonstrated that silylene-coinage metal complexes exhibit catalytic efficiency towards hydrosilylation, copper-catalyzed alkyne azide cycloaddition (CuAAC), and glycosidation reactions. Although the chemistry of silylene-coinage metal complexes has only begun to blossom, these findings justify the need for a review at this stage of development. This article will summarize the previous work on silylene-coinage metal complexes followed by recent advances and conclude with future possibilities.
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