Journal
CHEMICAL COMMUNICATIONS
Volume 57, Issue 59, Pages 7264-7267Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc02114a
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Funding
- National Science Foundation [CHE-1925751]
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In this study, a stable Ni-III dichloride complex supported by a tetradentate pyridinophane N-donor ligand was isolated, characterized, and found to undergo efficient photoreductive chlorine elimination upon irradiation in both solution and solid-state. The (NiCl2)-Cl-III species can be regenerated via a reaction with PhICl2.
Herein we report the isolation, characterization, and photoreactivity of a stable Ni-III dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the (NiCl2)-Cl-III species can be regenerated via a reaction with PhICl2.
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