4.2 Article

Water-dispersible and ferroelectric PEGylated barium titanate nanoparticles

Journal

MATERIALS ADVANCES
Volume 2, Issue 15, Pages 5089-5095

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ma00317h

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Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada Excellence Research Chair (CERC) program
  3. University of Calgary's Global Research Initiative in Sustainable Low Carbon Unconventional Resources - Canada First Research Excellence Fund (CFREF)

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This research presents the development of highly dispersed nano-sized ferroelectric barium titanate powders using a simple, one-step low temperature solution method. The surface of these nanoparticles was modified with poly(ethylene glycol) as a stabilizer and dispersant. It was demonstrated that changing the reaction conditions allows for tuning the nanoparticle size.
Dispersions of ferroelectric nanoparticles in aqueous medium can find promising applications in electro-optical, medical, and smart fluid technologies. In this report, we show the development of highly dispersed nano-sized ferroelectric barium titanate (BaTiO3) powders with high dielectric constant prepared using a simple, one-step low temperature solution method. The surface of these tetragonal-structured nanoparticles were modified with poly(ethylene glycol) as a stabilizer and dispersant. The crystal structure, morphology and dielectric constant of samples are discussed in detail. The colloidal stability and surface behavior of these PEGylated barium titanate nanoparticles are studied by means of zeta-potential and dynamic light scattering measurements. We show changing the reaction conditions allows to tune the nanoparticle size. This research promotes a pathway to develop advanced ferroelectric nanomaterials with engineered properties in a simple way.

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