Journal
GREEN SYNTHESIS AND CATALYSIS
Volume 2, Issue 3, Pages 299-302Publisher
KEAI PUBLISHING LTD
DOI: 10.1016/j.gresc.2021.05.003
Keywords
Radical borylation; Arylboronates; Pyridinium-catalyzed; Decarboxylative borylation; Cross-coupling
Categories
Funding
- National Natural Science Foundation of China [21772046]
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
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A pyridinium salt catalyzed radical borylation of benzoyl peroxides has been reported in this study, which successfully produces various arylboronates at ambient temperature. This method is simple to operate and environmentally friendly due to being additive-and base-free, transition-metal-free, and mild in conditions.
A pyridinium salt catalyzed radical borylation of benzoyl peroxides is reported herein. A range of benzoyl peroxides having different electronic properties were well compatible in this borylation reaction, delivering various arylboronates in good yields at ambient temperature. The current method features simple operation, additive-and base-free, transition-metal-free and mild conditions.
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