Journal
POLYMER CHEMISTRY
Volume 12, Issue 31, Pages 4462-4466Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1py00780g
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Funding
- DoD [W911NF-17-1-0326]
- NSF [DMR-1904631]
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This study demonstrates the photoinduced intrachain crosslinking of coumarin-containing copolymers in various organic solvents, with solvophobicity-driven crosslinking kinetics and chain compaction facilitating the synthesis of single-chain nanoparticles.
We describe the photoinduced intrachain crosslinking of coumarin-containing copolymers in various organic solvents. Analysis of copolymer solvation and comparison to a molecular coumarin derivative revealed solvophobicity-driven crosslinking kinetics and chain compaction that facilitated the synthesis of single-chain nanoparticles.
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