4.4 Article

Improving high rate cycling limitations of thick sintered battery electrodes by mitigating molecular transport limitations through modifying electrode microstructure and electrolyte conductivity

Journal

MOLECULAR SYSTEMS DESIGN & ENGINEERING
Volume 6, Issue 9, Pages 708-712

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1me00082a

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Funding

  1. National Science Foundation [CMMI-1825338, CMMI-1825216]

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Thicker electrodes can increase energy density, but molecular transport limits the rate of charge/discharge; mitigating transport limitations by increasing electrolyte conductivity and aligning the pores in the electrode microstructure.
For batteries, thicker electrodes increase energy density, however, molecular transport limits the rate of charge/discharge for extracting large fractions of available energy. Mitigating transport limitations by increasing electrolyte conductivity and aligning the pores in the electrode microstructure are described.

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