Journal
CHEMICAL SCIENCE
Volume 12, Issue 34, Pages 11338-11346Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1sc03308e
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Funding
- Alexander von Humboldt Foundation
- Deutsche Forschungsgemeinschaft [CRC 858, CRC 1459]
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Molecular photoswitches are key in responsive materials development, offering unexpected properties and functions. The arylazoisoxazole molecular switch can efficiently undergo solid-to-liquid phase transitions and acid-gated photoswitchable surface adhesion under certain conditions.
Molecular photoswitches play a vital role in the development of responsive materials. These molecular building blocks are particularly attractive when multiple stimuli can be combined to bring about physical changes, sometimes leading to unexpected properties and functions. The arylazoisoxazole molecular switch was recently shown to be capable of efficient photoreversible solid-to-liquid phase transitions with application in photoswitchable surface adhesion. Here, we show that the arylazoisoxazole forms thermally stable and photoisomerisable protonated Z- and E-isomers in an apolar aprotic solvent when the pK(a) of the applied acid is sufficiently low. The tuning of isomerisation kinetics from days to seconds by the pK(a) of the acid not only opens up new reactivity in solution, but also the solid-state photoswitching of azoisoxazoles can be efficiently reversed with selected acid vapours, enabling acid-gated photoswitchable surface adhesion.
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