4.5 Article

Few-layered ultra-small MoS2 nanosheet cathode for high-performance rechargeable aluminum-ion battery

Journal

SUSTAINABLE ENERGY & FUELS
Volume 5, Issue 17, Pages 4289-4294

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1se00959a

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Funding

  1. Key Program of the Chinese Academy of Sciences [KGZD-EW-T08]
  2. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA22010601]
  3. Youth Innovation Promotion Association of the Chinese Academy of Sciences

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The few-layered ultra-small MoS2 nanosheets enhance performance and stability in aluminum-ion batteries by reducing electrostatic repulsion and mechanical stress, increasing active sites exposure, and shortening ion transport distance.
We report novel few-layered ultra-small MoS2 nanosheets, which significantly enhance kinetic performance and structural stability when employed as the cathode in the aluminum-ion battery (AIB). During Al3+ insertion, the few-layered structure weakens the electrostatic repulsion and the small size reduces the mechanical stress. Moreover, the high specific surface area exposes more active sites and increases the contact area between the active material and the electrolyte, shortening the ion transport distance.

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