4.7 Article

Dynamics of a [2]rotaxane wheel in a crystalline molecular solid

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 66, Pages 8210-8213

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03009d

Keywords

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Funding

  1. Natural Sciences and Engineering Research Council of Canada [RGPIN-2018_101694]
  2. Canada Research Chair
  3. Florida State University
  4. National High Magnetic Field Laboratory (NHMFL) - National Science Foundation [DMR-1644779]
  5. State of Florida
  6. University of Windsor
  7. Canadian Foundation for Innovation
  8. Ontario Innovation Trust
  9. Natural Sciences and Engineering Research Council [RGPIN-2016_06642]

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An H-shaped [2]rotaxane composed of a bis(benzimidazole) axle and a 24-membered crown ether wheel with four trityl groups forms a highly crystalline material allowing large amplitude motion of the interlocked macrocycle, characterized using variable-temperature (VT) H-2 solid-state nuclear magnetic resonance (SSNMR).
An H-shaped [2]rotaxane comprising a bis(benzimidazole) axle and a 24-membered crown ether wheel appended with four trityl groups forms a highly crystalline material with enough free volume to allow large amplitude motion of the interlocked macrocycle. Variable-temperature (VT) H-2 solid-state nuclear magnetic resonance (SSNMR) was used to characterize the dynamics of the [2]rotaxane wheel in this material.

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