4.7 Review

Recent advances in non-precious metal electrocatalysts for pH-universal hydrogen evolution reaction

Journal

GREEN ENERGY & ENVIRONMENT
Volume 6, Issue 4, Pages 458-478

Publisher

KEAI PUBLISHING LTD
DOI: 10.1016/j.gee.2020.10.013

Keywords

Electrocatalysis; Hydrogen evolution reaction; Transition metal; Nanomaterials; Water electrolysis

Funding

  1. National Natural Science Foundation of China [21671039, 21673241]
  2. Natural Science Foundation of Fujian Province [2015J01038]
  3. New Century Excellent Talents in Fujian Province University, State Key Laboratory of Structural Chemistry
  4. Program for Innovative Research Team in Science and Technology in Fujian Normal University (IRTSTFJ)

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This review summarizes recent progress in understanding the mechanism of non-precious metal electrocatalysts for pH-universal HER, and demonstrates general approaches to overcome the limitations of electrocatalysts in a broad pH range. It also proposes perspectives and challenges for the development of pH-universal HER electrocatalysts.
Hydrogen production by water electrolysis is a compelling technology to produce fuels and chemicals powered by renewable energy. It is highly desirable to develop cost-effective and durable electrocatalysts for hydrogen evolution reaction (HER). This review has summarized recent progress in mechanism understanding of non-precious metal electrocatalysts for pH-universal HER. The general approaches have been demonstrated to overcome the activity/stability limitations of the electrocatalysts for HER in a broad pH range. The perspectives and challenges for the development of pH-universal HER electrocatalysts have also been proposed. This review sheds light on the design and fabrication of high-performance electrocatalysts for versatile HER-related energy technologies. (C) 2020, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.

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